Product ID:ARDROX 9D6/D495A NON-AQUEOUS DEVELOPER
MSDS Date:06/22/1995
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKWJD

BRENT AMERICA, INC.

16961 KNOTT AVE.
LA MIRADA, CA 90638-6015
US

Emergency Phone: (800)424-9300

Info Phone: 714-739-2821

Preparer: STEPHEN MORRIS

Cage: 23373

BRENT AMERICA, INC

ARLINGTON, TN 38002 US

Telephone: 901-867-9400

Cage: UO126

1,1,1-TRICHLORETHANE

CAS: 71-55-6

RTECS: KJ2975000

OSHA PEL 1900 MG/M3;350 PPM

ACGIH TLV: 1910 MG/M3;350 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SEC-BUTYL ALCOHOL

CAS: 78-92-2

RTECS: EO1750000

OSHA PEL 450 MG/M3;150 PPM

ACGIH TLV: 303 MG/M3;100 PPM

QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL see Table Z-3

ACGIH TLV: 0.1 MG/M3

CALCIUM CARBONATE

CAS: 471-34-1

RTECS: FF9335000

OSHA PEL 15 MG/M3 (TDUST)

ACGIH TLV: 10 MG/M3 (TDUST)

LD50 LC50 Mixture:NOT PROVIDED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:BREATHED: MAY CAUSE IRRITATION TO
RESPIRATORY SYSTEM, CNS DEPRESSION WITH SYMPTOMS OF HEADACHE,
DIZZINESS, NAUSEA, UNCONSCIOUSNESS, POSSIBLE CNS DAMAGE AND MAY
EVEN BE FATAL IN CONFINED/POORLY VENTILA TED AREAS. SKIN CONTACT:
PROLONGED AND REPEATED CONTACT CAN CAUSE DEFATTING, DRYING, SEVERE
IRRITATION, DERMITITIS. UNLIKELY TO BE ABSORBED THROUGH SKIN IN
HARMFUL CONCENTRATIONS. EYE CONTACT: WILL CA USE PAINFUL
BURNING/STINGING, WATERING AND INFLAMMATION. SWALLOWED: MAY RESULT
IN VOMITING. ASPIRATION MAY CAUSE LUNG DAMAGE AND PULMONARY EDEMA
OR HEMORRHAGE. SWALLOWING A COMPONENT MAY CAUSE UNCONS CIOUSNESS.
Explanation of Carcinogenicity:CONTAINS QUARTZ.
Effects of Overexposure:BREATHED: MAY CAUSE IRRITATION TO RESPIRATORY
SYSTEM, CNS DEPRESSION WITH SYMPTOMS OF HEADACHE, DIZZINESS,
NAUSEA, UNCONSCIOUSNESS, POSSIBLE CNS DAMAGE AND MAY EVEN BE FATAL
IN CONFINED/POORLY VENTILA TED AREAS. SKIN CONTACT: PROLONGED AND
REPEATED CONTACT CAN CAUSE DEFATTING, DRYING, SEVERE IRRITATION,
DERMITITIS. EYE CONTACT: WILL CAUSE PAINFUL BURNING/STINGING,
WATERING AND INFLAMMATION. SWALLO WED: MAY RESULT IN VOMITING.
SWALLOWING A COMPONENT MAY CAUSE UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN, CENTRAL
NERVOUS SYSTEM, RESPIRATORY OR CARDIAC DISORDERS MAY CAUSE ALLERGIC
DERMITITIS.

First Aid:BREATHED: REMOVE TO FRESH AIR AT ONCE. IF NOT BREATHING, GIVE
MOUTH-TO-MOUTH RESUSCITATION. IF BREATHING IS DIFFICULT, GET
IMMEDIATE MEDICAL ATTENTION. SKIN: WASH IMMEDIATELY WITH SOAP AND
WATER. GET MEDICAL ATTENTION IF ILL EFFECTS/IRRITATION DEVELOPS.
EYES: WASH IMMEDIATELY WITH WATER FOR AT LEAST 20 MINUTES. ASSURE
THAT EYELIDS ARE SEPARATED. LIFT LOWER AND UPPER LID OCCASIONALLY.
GET IMMEDIATE MEDICAL ATTENTION. SWALLOWED: DO NOT INDUCE
VOMITING. IF VOMITING OCCURS SPONTANEOUSLY, DO NOT ALLOW VOMITUS TO
BE BREATHED INTO LUNGS. KEEP VICTIM'S HEAD BELOW HIS HIPS. CALL
PHYSICIAN IMMEDIATELY. IF CONSCIOUS, DRINK 2 GLASSES OF WATER.

Flash Point Method:PMCC
Flash Point:>93.3C, 200.F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:DRY CHEMICAL. ALCOHOL RESISTANT FOAM. CO2. WATER
SPRAY.
Fire Fighting Procedures:SELF-CONTAINED BREATHING EQUIPMENT SHOULD BE
USED IN CONFINED AREAS WHERE THE SOLVENT IS STORED.
Unusual Fire/Explosion Hazard:DECOMPOSES WITH FIRE OR HOT SURFACES TO
ACIDIC GASES AND OTHER HIGHLY TOXIC SUBSTANCES. POSSIBILITY OF
PHOSGENE GAS FORMATION.

Spill Release Procedures:SMALL SPILL: MOP UP OR SOAK UP WITH
NON-COMBUSTIBLE ABSORBENT INORGANIC MATERIAL. TRANSFER TO
DOT-APPROVED CONTAINER. LARGE SPILLS SHOULD BE REMOVED BY VACUUM
TRUCK. THIS SOLVENT IS NORMALLY RECYCLABL E. IF CONDITIONS PREVENT
RECYCLING, DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND
LOCAL HEALTH AND POLLUTION REGULATIONS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:KEEP CONTAINERS COOL, DRY, AND AWAY
FROM SOURCES OF IGNITION. DO NOT STORE PRODUCT IN DIRECT SUNLIGHT,
HIGH TEMPERATURE, OR BELOW FREEZING AREAS. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE.
USE AND STORE WITH ADEQUATE VENTILATION.
Other Precautions:TRAIN ALL EMPLOYEES ON ALL SPECIAL HANDLING
PROCEDURES BEFORE THEY WORK WITH THIS PRODUCT. EXERCISE REASONABLE
CARE AND CAUTION. PERSONNEL SHOULD AVOID BREATHING VAPORS AND/OR
MISTS AND GETTING PRODUC T IN THE EYES OR ON THE SKIN. DO NOT
CONSUME FOOD, DRINK, OR TOBACCO IN STORAGE AREA. VAPORS ARE HEA
VIER THAN AIR.

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
EXPOSURE GUIDELINES. WHEN RESPIRATORY PROTECTION IS REQUIRED, USE A
NIOSH/MSHA APPROVED FILTER TYPE RESPIRATOR USED IN ACCORDANCE WITH
29 CFR 1910.134. IN CONFINED/POORLY VENTILATED AREAS OR FOR
EMERGENCY, USE AN APPROVED POSITIVE-PRESSURE, SELF-CONTAINED
BREATHING APPARATUS OR AIR LINE SUPPLIED RESPIRATOR.
Ventilation:CONTROL AIRBORN CONCENTRATIONS BELOW EXPOSURE GUIDELINES
WITH MECHANICAL VENTILATION. LETHAL CONCENTRATIONS MAY EXIST IN
AREAS WITH POOR VENTILATION.
Protective Gloves:IMPERMEABLE GLOVES
Eye Protection:SAFETY GLASSES, CHEMICAL GOGGLES AND FACE SHIELD
Other Protective Equipment:FOR PROLONGED/REPEATED CONTACT, USE
PROTECTIVE CLOTHING. SELECTION OF SPECIFIC ITEMS SUCH AS BOOTS,
APRON, OR FULL-BODY SUIT WILL DEPEND ON OPERATION. SAFETY SHOWERS,
EYE WASHES AND FIRE EXTINGUISHERS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING CHEMICALS.
Supplemental Safety and Health
P/N: 12261. ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE.
N/K=UNKNOWN. N/P=NOT PROVIDED. N/R=NOT RELEVANT. N/D=NOT
DETERMINED. N/E=NOT ESTABLISHED. CNS=CENTRAL NERVOUS SYSTEM.
GI=GASTROINTESTINAL .

HCC:T4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=73.9C, 165.F
Melt/Freeze Pt:M.P/F.P Text:NOT DETERMINED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:110
Vapor Density:4.5
Spec Gravity:1.36
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:6.0 (BUAC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE POWDER SUSPENDED IN COLORLESS LIQUID;
ETHER-LIKE ODOR.
Percent Volatiles by Volume:NOT PROVIDED
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES(SUCH AS SODIUM HYDROXIDE), AND ALKALI METALS. DO NOT
STORE IN CONTACT WITH ALUMINUM.
Stability Condition to Avoid:HEAT. FLAMES AND SPARKS. IGNITION SOURCES.
Hazardous Decomposition Products:HCL GAS. POSSIBLY TRACES OF TOXIC
PHOSGENE. TOXIC FUMES WHEN HEATED TO DECOMPOSITION.

Waste Disposal Methods:HANDLE WASTE SOLVENT AS HAZARDOUS WASTE. COLLECT
INTO DOT APPROVED CONTAINER. THIS WASTE COULD BE STABILIZED,
SOLIDIFIED, INCINERATED. FOR MORE INFORMATION CONSULT CFR 40.
COMPLY WITH ALL APPLICABLE G OVERNMENTAL REGULATIONS ON SPILL
REPORTING AND HANDLING AND DISPOSAL OF WASTE.

Toxicological Information:NOTE TO PHYSICIAN: SUPPORTIVE CARE. TREATMENT
BASED ON JUDGEMENT OF PHYSICIAN IN RESPONSE TO REACTIONS OF
PATIENT. NEVER ADMINISTER ADRENALIN FOR SWALLOWING OR INHALATION
OVEREXPOSURE. INCREASED SENSI TIVITY OF THE HEART TO ADRENALIN MAY
BE CAUSED BY OVEREXPOSURE TO THIS PRODUCT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT PROVIDED

Transport Information:DOT INFORAMTION: 1,1,1-TRICHLORETHANE,
6.1,UN2831, PG I I I.

SARA Title III Information:SECT 302-304: THRESHOLD PLANNING QUANTITY
(TPQ): NONE. REPORTABLE QUANTITY (RQ): 1100 LBS
(1,1,1-TRICHLORETHANE). SECTION 311-312: NONE. CHEMICAL(S) SUBJECT
TO THE REPORTING REQUIREMENTS OF SECTION 31 3 OF TITLE III OF THE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40
CFR PART 372: 1,1,1-TRICHLORETHANE AND SEC-BUTYL ALCOHOL.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER OR REPRODUCTIVE TOXICITY. THESE ARE TRACE AMOUNTS FOUND IN
NORMAL TECHNICAL GRADE INDUSTRIA L MATERIALS AND ARE NOT
DELIBERATELY ADDED TO THE PRODUCT.